Corrosion Behaviour of Brass, Galvanized Steel and Stainless Steel in Blends of Jatropha Biodiesel and Diesel
Keywords:
Jatropha biodiesel, Corrosion, Acid Value, Stainless Steel, Galvanized Steel, Brass, FuelAbstract
The corrosion behaviour of brass (Br), galvanized steel (GS) and stainless steel (SS) on exposure to Jatropha biodiesel and its blend with petroleum–based diesel was investigated in this study. Jatropha biodiesel was produced via transesterification reaction with methanol using sodium hydroxide as catalyst. Corrosion rates of these metals were evaluated using weight loss method after the metals were immersed in the fuels for 8 weeks. The acid value (AV), peroxide value (PV) and iodine value (IV) of the fuels during the immersion test were analysed. The degradation of the metal surfaces and the colour of the biodiesel fuel at the end of the immersion test were also characterized by visual inspection. The corrosion rate of Br, GS and SS in Jatropha biodiesel after 8 weeks (56 days) of exposure was 0.6091, 0.3435 and 0.053 mpy respectively. As the volume of diesel was increased in the blend, the corrosion rates of the alloys decreased. There was increase in both the AV and PV during the immersion test with the fuel containing Br having the highest value. A decrease was observed in the IV of the Jatropha biodiesel during the immersion period. Changes in colour were also observed for the biodiesel containing the metals.
References
Ahmad, Z. (2006). “Principles of Corrosion Engineering and Corrosion Control,” Butterworth – Heinemann, Burlinton, pp. 136.
Akhabue, C. E., Iworah J.C. and Aisien F.A. Effect of Selected Metal Contaminants on the Stability of Castor Oil Methyl Ester, Journal of Fuels, volume 2014; Article ID 641849, 6 pages http://dx.doi.org/10.1155/2014/641849, 2014.
American Oil Chemists Society – AOCS. Official and tentative methods, (3rd ed.), Chigago, 1997.
Chew, K. V., Haseeb, A. S. M. A., Masjuki, H. H., Fazal, M. A. and Gupta, M. Corrosion of magnesium and aluminium in palm biodiesel: A comparative evaluation. Energy 57, 478 – 483, 2013.
Cursaru, D., Branoiu, G., Ramadan, I. and Miculescu, F. Degradation of automotive materials upon exposure to sunflower biodiesel, Industrial Crops and Products, 54, 149 – 158, 2014.
Diaz-Ballote, L. Lopez-Sansores, J. F., Maldonado – Lopez, L. and Garfias-Mesias, L. F. Corrosion behaviour of aluminium exposed to a biodiesel. Electrochemistry Communication 11, 41 – 44, 2009.
Fazal, M. A., Haseeb, A. S. M. A., and Masjuki, H. H. Comparative corrosion characteristics of petroleum diesel and palm biodiesel for automotive materials. Fuel Processing Technology 91, 1308 – 1315, 2010.
Fazal, M. A., Haseeb, A. S. M. A., and Masjuki, H. H. Effect of temperature on the corrosion behaviour of mild steel upon exposure to palm biodiesel. Energy 36, 3328 – 3334, 2011.
Fazal, M. A., Haseeb, A. S. M. A. and Masjuki, H. H. Degradation of automotive materials in palm biodiesel. Energy 40, 76 – 83, 2012.
Fazal, M. A., Haseeb, A. S. M. A., and Masjuki, H. H. Corrosion mechanism of copper in palm biodiesel, Corrosion Science, 67, 55 – 59, 2013.
Fernandes, D. M., Montes, R. H. O., Almeida, E. S., Nascimento, A. N., Oliveira, P. V., Ritcher, E. M. and Munoz, R. A. A. Storage stability and corrosive character of stabilized biodiesel exposed to carbon and galvanized steels. Fuel 107, 609 – 614, 2013.
Firestone, D. Official methods and recommended practices of the American Oil Chemists’ Society (5th ed.). Champaign, Illinois: AOCS, 1998.
Fontana, M. G. Corrosion Engineering, 3rd ed. New York, McGraw Hill, 1987.
Haseeb, S. M., Masjuki, H. H., Ann, L. J. and Fazal, M. A. “Corrosion characteristics of copper and leaded bronze in palm biodiesel”. Fuel Processing and Technology 91, 329–334, 2010.
Hu, E., Xu, Y., Hu, X., Pan, L., Jiang, S. Corrosion behaviors of metals in biodiesel from rapeseed oil and methanol. Renewable Energy 37, 371 – 378, 2012.
Knothe, G. Dependence of biodiesel fuel properties on the structure of fatty acid alkyl esters. Fuel Processing and Technology 86, 1059 – 1070, 2005.
Knothe, G., Dunn, R. O. and Bagby, M. O. “Biodiesel: the use of vegetable oils and their derivatives as alternative diesel fuels”. American Chemical Society, First Edition. pp. 358-390, 1997.
Pullen, J., and Saeed, K. An overview of biodiesel oxidative stability, Renewable and Sustainable Energy Reviews 16, 5924 – 5950, 2012.
Sarin, A., Arora, R., Singh, N., Sarin, R., and Malhotra, R. K. Blends of biodiesel synthetized from non-edible and edible oils: Influence on OS (oxidative stability), Energy 35, 3449 – 3453, 2010.
Wang, W., Jenkins, P. E. and Ren, Z. “Heterogeneous corrosion behaviour of carbon steel in water contaminated biodiesel”. Corrosion Science 53, 845–849, 2011.